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This causes oxidativeaddition to become the rate-limiting step in the 1,10-phenanthroline-mediated reaction.
2
The immediate product of the oxidativeaddition step is found to undergo facile reductive elimination to provide the arylation product.
3
It is suggested that the formation of a T-shaped intermediate could foster the C-H activation via oxidativeaddition to the metal centre.
4
Because O-coordination of a deprotonated amino alcohol is favored over N-coordination in the oxidativeaddition transition state, O-arylation is favored with the 1,10-phenanthroline ligand.
Usage of reductive elimination in английском
1
The immediate product of the oxidative addition step is found to undergo facile reductiveelimination to provide the arylation product.
2
The 1H NMR study indicated the reductiveelimination of the p-toluenesulfonyl group from Ts-OF in the presence of antioxidants and photo-irradiation.
3
Electrons transferred from NADPH via cytosolic flavoprotein oxidoreductases are used to cleave the cobalt-carbon bond with reductiveelimination of the cyanide ligand.
4
Using strategies based on enzymatic, chemical, and mass spectrometric analysis, we have defined the structures of the major glycans released by reductiveelimination from GCX.
5
A highly reactive seven-membered Mn(I) intermediate is detected and characterized that is effective for H-transfer or reductiveelimination to deliver alkenylated or pyridinium products, respectively.
6
The selectivity between the (5 + 2) and homo-ene products is determined in the subsequent competing reductiveelimination and β-hydride elimination steps.